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A comparison of in situ vs. ex situ filtration methods on the assessment of dissolved and particulate metals at hydrothermal vents ArchiMer
Cotte, Laura; Waeles, Mathieu; Pernet-coudrier, Benoit; Sarradin, Pierre-marie; Cathalot, Cecile; Riso, Ricardo D..
The objective of this study was to assess the impact of the filtration method (in situ vs. ex situ) on the dissolved/particulate partitioning of 12 elements in hydrothermal samples collected from the Lucky Strike vent field (Mid-Atlantic Ridge; MAR). To do so, dissolved ( <0.45 mu m) and particulate Mg, Li, Mn, U, V, As, Ba, Fe, Zn, Cd, Pb and Cu were measured using different techniques (HR-ICP-MS, ICP-AES and CCSA). Using in situ filtration as a baseline, we showed that ex situ filtration (on-board and on shore after freezing) resulted in an underestimation of the dissolved pool, which was counterbalanced by an overestimation of the particulate pool for almost all the elements studied. We also showed that on-board filtration was acceptable for the...
Tipo: Text Palavras-chave: Metal; Hydrothermal vent; Dissolved; Particulate; Filtration method.
Ano: 2015 URL: https://archimer.ifremer.fr/doc/00298/40970/42656.pdf
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Dissolved and particulate metals (Fe, Zn, Cu, Cd, Pb) in two habitats from an active hydrothermal field on the EPR at 13 degrees N ArchiMer
Sarradin, Pierre-marie; Lannuzel, D; Waeles, M; Crassous, Philippe; Le Bris, Nadine; Caprais, Jean-claude; Fouquet, Yves; Fabri, Marie-claire; Riso, R.
The distribution of Fe, Cu, Zn, Pb, Cd between the dissolved (<2 mu m) and the particulate (>2 mu m) fractions was measured after in-situ filtration in two hydrothermal habitats. The total metal concentration ranges exhibit a clear enrichment compared with the seawater concentration, accounting for the hydrothermal input for all the metals considered. Iron is the predominant metal (5-50 mu M) followed by Zn and Cu. Cd and Pb are present at the nM level. At the scale studied, the behavior of temperature, pH and dissolved iron is semi-conservative whereas the other dissolved and particulate metals are characterized by non-conservative patterns. The metal enrichment of the >2 mu m fraction results from the settlement and accumulation of particulate...
Tipo: Text Palavras-chave: Hydrothermal fauna; Habitats; Particulate; Dissolved; Metals.
Ano: 2008 URL: http://archimer.ifremer.fr/doc/2008/publication-3830.pdf
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Iron isotope fractionation in iron-organic matter associations: Experimental evidence using filtration and ultrafiltration ArchiMer
Lotfi-kalahroodi, Elaheh; Pierson-wickmann, Anne-catherine; Guénet, Hélène; Rouxel, Olivier; Ponzevera, Emmanuel; Bouhnik-lecoz, Martine; Vantelon, Delphine; Dia, Aliou; Davranche, Mélanie.
Colloids have been recognized as key vectors of pollutants in aqueous environment. Amongst them, those formed by iron (Fe) and organic matter (OM) are of major importance due to their ubiquity in the surface environment and strong affinity for metals. In the recent years, Fe stable isotopes have been increasingly used to elucidate the sources and biogeochemical cycling of Fe in Earth's surface environments. In this study, we aim to elucidate (i) the possible Fe isotopic signature resulting from the Fe/OM colloid formation and (ii) the mechanisms involved in the development of such isotopic signature. For this purpose, Fe-OM associations were synthesized through binding and titration experiments. Various pH levels were used in order to study the isotope...
Tipo: Text Palavras-chave: Filtration; Size fractionation; Isotope fractionation; Colloidal; Dissolved; Fe isotopes.
Ano: 2019 URL: https://archimer.ifremer.fr/doc/00480/59174/61811.pdf
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